Palladium-catalyzed selective fluorination of o-carboranes.
نویسندگان
چکیده
A Pd(II)-catalyzed direct selective fluorination reaction of carboranes using a F(+) reagent has been developed, leading to a series of polyfluorocarboranes in high isolated yields. The mechanism involving electrophilic B-H activation, oxidation of Pd(II) by F(+) species, and reductive elimination is proposed.
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 135 33 شماره
صفحات -
تاریخ انتشار 2013